Issue Dispersion Effects
Editor: Benjamin List
Guest Editors: Peter R. Scheiner, Stefan Grimme
分散相互作用是立体排斥的对应物，在有机合成的经典模型中得到了很好的应用。在过去的几年里，很明显，这两者的相互作用对于理解热力学稳定性、分子识别、通过过渡态稳定的化学选择性、蛋白质折叠、酶的催化作用等是至关重要的。现在人们对分散性有了更多的了解，但还没有达到在合成计划中常规纳入的程度。因此，合理利用分散性作为合成中的一个战略要素是一个及时的问题。
Enhancement of London Dispersion in Frustrated Lewis Pairs: Towards a Crystalline Encounter Complex
Holtrop, Flip; Helling, Christoph; Lutz, Martin; van Leest, Nicolaas P.; de Bruin, Bas; Slootweg, J. Chris
Loir-Mongazon, Lucas; Antuña-Hörlein, Carmen; Deraedt, Christophe; Cornaton, Yann; Djukic, Jean-Pierre
London Dispersion-Assisted Low-Temperature Gas Phase Synthesis of Hydrogen Bond-Inserted Complexes
Lange, Manuel; Sennert, Elisabeth; Suhm, Martin A.
Efficient Computation of the Interaction Energies of Very Large Non-covalently Bound Complexes
Gorges, Johannes; Bädorf, Benedikt; Grimme, Stefan; Hansen, Andreas
London Dispersion Stabilizes Chloro-Substituted cis-Double Bonds
Rummel, Lars; Hanke, Kai; Becker, Jonathan; Schreiner, Peter R.
Zhai, Jianyu; Reid, Jolene P.
Ultralong C(sp3)–C(sp3) Single Bonds Shortened and Stabilized by London Dispersion
Shimajiri, Takuya; Kawakami, Yuta; Kawaguchi, Soki; Hayashi, Yuki; Hada, Kazuto; Suzuki, Takanori; Ishigaki, Yusuke
Schatz, Dominic; Kunz, Anne; Raab, Aileen R.; Wegner, Hermann A.
Verevkin, Sergey P.; Samarov, Artemiy A.; Zherikova, Kseniya V.
