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Chemistry at Thieme | 7月有机化学内容精选 2025-07-15

Thieme有机化学最新一期的精选内容来了!

本期我们将深入探讨可持续发展与合成材料创新领域的关键进展。不要错过Zuin等人撰写的重要文献综述,该研究揭示了再生塑料玩具的潜在风险——这一议题在儿童安全与循环经济的交叉领域具有紧迫性。同时值得关注还有Gupta等人的研究成果,他们不仅强调了聚烯烃在可持续塑料发展中的重要角色,更揭示了人工智能驱动的回收技术所蕴含的激动人心的潜力。

Sustainability & Circularity NOW

Highlight Articles


The Hidden Risks of Recycled Plastic Toys: A Literature Review on Legacy Additives and Child Safety

Zuin Zeidler Vânia G. et al.

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Discover this review by Zuin et al. which explores the hidden risks of recycled plastic toys, revealing how legacy additives threaten child safety and hinder sustainable recycling.

Polyolefins in the Circular Economy: Advances and Recyclability

Gupta Virendrakumar

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Read this insightful review by Gupta et al. The article examines the role of polyolefins in the circular economy, highlighting recycling advancements, environmental challenges, and the potential of AI-driven innovations for a sustainable plastic value chain.

Synthesis

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Synthesis of 3,5-Disubstituted Anilines via Sequential Mo-Catalyzed Deoxygenative Benzene Formation and Pd-Catalyzed Amination Reactions

G. Fang et al.

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Delve into this feature article from Zhuo et al. presenting an efficient route to 3,5-disubstituted anilines via sequential Mo- and Pd-catalyzed transformations, achieving high yields from simple starting materials.

Metal-Free and Scalable Sulfoxide Reduction through the Couple (COCl)2/Et3SiH: Synthesis of Albendazole Hydrochloride

C. Morales-Manrique et al.

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Explore the work by Gamba-Sánchez et al., showcasing a metal-free, scalable sulfoxide reduction method applied to the synthesis of albendazole hydrochloride with excellent yield and greener conditions.

Photocatalytic Strategies for the Synthesis of Xanthates and Their Analogues

L. Geniller et al.

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Uncover the latest advances by Prieto et al., reviewing innovative photocatalytic strategies for synthesizing xanthates and their analogues, highlighting efficient and diverse photochemical methods.

Stereoselective Synthesis of Benzosultam-Fused Tetrahydroquinazolines via [4+2]-Cycloaddition of Cyclic N-Sulfonyl Ketimines with 2-Aminophenyl Enones

J. W. Han, S.-G. Kim

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Discover the work of Kim et al. on a stereoselective [4+2]-cycloaddition method enabling efficient access to benzosultam-fused tetrahydroquinazolines with high yields and excellent diastereoselectivity.

Synlett

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Recent Advances in the Synthesis of Functionalized Pyrazolo[1,5-a]pyrimidines via C–H Functionalization

S. Paul et al.

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Check out recent sustainable strategies for C–H functionalization in the synthesis of functionalized pyrazolo[1,5-a]pyrimidines by Bagdi et al.

An Oxygen Walk Approach for C3 Selective Hydroxylation of Pyridines

C.-Y. Cai, T. Qin

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Take a closer look at Qin et al.’s innovative oxygen walk strategy enabling direct C3-selective hydroxylation of pyridines through photoinduced valence isomerization of pyridine N-oxides.

Cyclic Imine-BF3 Complexes as Precursors for Functionalized Azacycles

K. Bhatt, D. Seidel

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Gain insights into the use of stable cyclic imine–BF₃ complexes as versatile precursors for functionalized azacycles in this study by Seidel et al.

Enantioselective 1,4-Borylamination Enabled by Copper Catalysis

Y.-s. Zhu, B. Su

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Read about the copper-catalyzed enantioselective 1,4-borylamination strategy by Su et al., offering access to versatile 4-aminoalkylboronates with high selectivity.

SynOpen

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Study on the Synthesis and Biological Activity of Trifluoroacetamide Promoted by Base without Transition-Metal Participation

X. Tian et al.

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Discover a transition-metal-free method for synthesizing trifluoroacetylanilines by Li et al., featuring mild conditions and promising bactericidal activity.