Cookie-Einstellungen
     
 
 
新闻
SynOpen: Highlighted article from issue 1/2024 2024-03-12

Highlight Article

letter

tert-Butoxide-Mediated Protodeformylative Decarbonylation of α-Quaternary Homobenzaldehydes

Benjamin J. Stokes, Xiao Cai, Ritter V. Amsbaugh, Lauren J. Drake, Ravi M. A. Kotamraju, Nicholas Javier C. Licauco

Abstract

CC BY 4.0 · SynOpen 2024; 08(01): 47-50
DOI: 10.1055/a-2231-3108

tert-Butoxide mediates the Haller–Bauer-type (protodeformylative) decarbonylation of readily accessed α-quaternary homobenzaldehydes and related compounds at room temperature, generating cumene products. Both geminal dialkyl and geminal diaryl substituents are tolerated. gem-Dimethyls are sufficient for decarbonylation of polycyclic arenyl substrates whereas monocyclic aromatic homobenzaldehydes require cyclic gem-dialkyls or gem-diaryls for significant decarbonylation.

i_t0072_ga_10-1055_a-2231-3108.gif

阅读 Issue 01/2024 全部论文,点击这里

Upcoming Special Topics

▪ 如果您准备投稿,请先与通讯(客座)编辑联系,并要包括稿件标题及类型(例如,评论、简评或原创论文)。

▪ 经通讯(客座)编辑同意后,您即可根据作者指南相关要求提交稿件。

▪ 在投稿过程中,请包括Special Topic的标题和相应的通讯编辑。

Polymer Chemistry

截止日期:2024年4月30日

联系邮箱Chemistry_invitations@thieme.de

This Special Issue looks to highlight advances in polymer materials with an emphasis on the synthetic methods and work involved. We welcome contributions from in the field spanning a range of subtopics, for example, work on monomer and polymer synthesis, biopolymers, recyclable and smart and sustainable polymers, polymerization catalysts, and functionalization methods.


了解更多 → 

Heterocyclic Chemistry

截止日期:2024年4月30日

联系邮箱: Chemistry_invitations@thieme.de

Heterocyclic compounds play a crucial role in various biological, medicinal, and industrial applications today. They are diverse and multifaceted in their use and as such, we wish to highlight advances in the field of synthetic heterocyclic chemistry. Topics in this special collection will include natural product synthesis, catalysis, coordination chemistry, materials science and biochemistry.


了解更多 →